explain the consiquences of lanthanide contraction plz send me a link of video too i need it please help

The consequences of lanthanide contraction are:

  1. With increase in atomic number of lanthanides there is a decrease in the basic character of lanthanide hydroxides. So, we see that La(OH)3 is the most basic while Lu(OH)3 is the least basic.  Because of the contraction there is a decrease in size of M3+ cation and this decreases the ionic character between the cation and OH- ion. Thus, there is a reduced basic character.

  2. The elements that come after lanthanides are affected by lanthanide contraction. The atomic radii of period 6 elements is similar to that of elements of period 5. Thus, radii of period 6 elements are smaller than would’ve been expected in the absence of lanthanides.
  3. Because of smaller size of period 6 elements, and the fact that they are very tightly packed in their metallic crystal that they have very high densities. The densities of elements in third transition series is almost double that of elements in the second transition series.
  4. The ionic size of Y3+ and Fr3+ is similar with similar charges. There is a large similarity in the crystal structure, chemical properties and solubility between Yttrium compounds and compounds of other heavier lanthanides.  Thus, Yttrium is regarded as a lanthanide.

You can refer to the given link for video:

http://cbse.meritnation.com/study-online/study-material/saTUraHv$y6GSj4WRzsU1Q!!/BRNrbwiCb3KX0fqDlEYSZQ!!

 

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