Explain the mechanism of cleansing action of soap?

 When soap molecules are present in water, the molecules arrange themselves in the form of a cluster in such a manner that their hydrophobic ends are away from the water molecules and their hydrophilic or ionic ends are towards the water molecules, as shown in the figure. This is known as micelle formation.

 

Micelle formation

 

Cleansing action of soaps: The dirt (oil and grease) present on clothes is organic in nature, and insoluble in water. Hence, it cannot be removed only by washing with water. When soap is dissolved in water, its hydrophobic ends attach themselves to the dirt and remove it from the cloth, as shown sequentially in the following figure.

Then, the molecules of soap arrange themselves in micelle formation and trap the dirt at the centre of the cluster. These micelles remain suspended in water like particles in a colloidal solution. The various micelles present in water do not come together to form a precipitate as each micelle repels the others because of ion-ion repulsion. Thus, the dust particles remain trapped in the micelles (which remain suspended), and are easily rinsed away by water. Hence, soap micelles remove the dirt by dissolving it in water.

  • 62

Each soap molecule has two ends. These are:

  • Polar, ionic hydrophilic end (water loving part)
  • Non-polar, non-ionic hydrophobic end (water hating part)

Dust or oil are hydrophobic in nature.

Mechanism of cleansing action of soap:

I. Soap gets dissolved in water.

ii. The non-polar ends get directed towards the centre and the polar ends get directed outwards.

iii. A cluster comprising of this arrangement is formed which is known as micelle.

iv. Dirty cloth is put in soap solution.

v. Non-polar end gets attached to the oil or dirt present in the cloth and polar end remain attached to water.

vi. Dirty cloth is agitated in soap solution.

vii. Oily and greasy particles entrapped in soap micelle gets dispersed in water.

vii. Soap water gets dirty and the cloth gets cleaned.

  • 41
What are you looking for?