HCL is a gas where as HF liquid at room temp.?

Hydrogen fluoride has a very strong permanent dipole, and so it forms stronger permanent dipole-permanent dipole forces with other HF molecules. The strength of these permanent dipoles is caused by the electronegativity of fluorine, being 4.0 and the highest. Therefore, HF molecules are very polar, i.e. they have a negative end (fluorine end) and a positive end (hydrogen). This polarity greatly attracts other HF molecules towards each. Hydrogen bonding is also present in between HF molecules, which creates large attractions between a H atom of a HF molecule and an F atom of other HF molecules. These factors make HF a liquid at room temperature.

 

Hydrogen chloride does not contain hydrogen bonding, despite chlorine having the same electronegativity as nitrogen, oxygen and fluorine do. The reason for this is that a chlorine atom is much bigger than atoms of oxygen, fluorine, or nitrogen, and so there is not as strong an attraction between a chlorine atom of one HCl molecule and a hydrogen atom of another HCl molecule. These factors make HCl a gas at room temperature.

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