how can I know that the given constituent liquids will show positive deviation or negative from the Raoult's law ??? how can I check it ??

The type of deviation depends on the type of intermolecular forces between the molecules.

Kindly referto the following link:
https://www.meritnation.com/ask-answer/question/im-having-a-bit-of-a-confusion-regarding-positive-and-negati/solutions/7156517

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