how was diffusion discovered and who discovered it?

by robert brown in 1827. Robert Brown is credited with being the firs t one to discover random motions of pollen grains while studying them through his microscope
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In 1829 Thomas Graham used an apparatus similar to the one shown in Figure 4.15 to study the diffusion of gases -- the rate at which two gases mix. This apparatus consists of a glass tube sealed at one end with plaster that has holes large enough to allow a gas to enter or leave the tube. When the tube is filled with H2 gas, the level of water in the tube slowly rises because the H2 molecules inside the tube escape through the holes in the plaster more rapidly than the molecules in air can enter the tube. By studying the rate at which the water level in this apparatus changed, Graham was able to obtain data on the rate at which different gases mixed with air.
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