in the geometry of ClF3 which is T shaped why are the 2 lone pair of electrons not placed at axial position
There are three possible structures of ClF3
(i) When lone pairs on equatorial positions
(ii) When one lone pair on axial and one lone pair on equatorial position
(iii) When two lone pairs on axial positions
Structure (i) is most stable because it has minimum lp – lp repulsion (compared to( ii) and minimum lp – bp repulsions (compared to( iii).
Since structure (i) is most stable structure of ClF3, Due to this reason the 2 lone pair of electrons not placed at axial position