plz Give the definitions of primary valence and secondary valance of metals?

 

  Primary Valency

Secondary Valency

Primary valency may be defined as +ve charge raised over central metal ion as its oxidation state

Secondary valency may be defined as no of mono dentate or equivalent to mondentate ligand attached to central metal ion. It defines the Coordination No.

 It is ionisable and variable

It is non ionisable and fixed


Example: [Cr(H2O)6]Cl3 = Primary valency is Chloride ion.

  Secondary valency is H2O molecules.

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