Show that in case of first order reaction, the time required for 99.9% of the reaction to complete is 10 times that required for half of the reaction to take place?
The integrated rate expression for first order reaction is
t= log ()
where a= initial concentration of reactants
a-x = concentration of reactants left.
so if the 99.9% of the reaction is complete then 0.1 % of the reaction is left.
Let a= 100 , and if 0.1 % reaction is incomplete, then a-x would be 0.1
now, using formulae given above, we can calculate the time period of the reaction.
t99.9= log()
t99.9= log (1000)............................{log1000=3}
t99.9 = 3.................. (1)
now, calculating time period for 50% completion of reaction,
t50= log()
t50= log(2)
t50= ......................(2)
Dividing equation 2 by 1
=
therefore, t99.9 = 10 t50