Show that in case of first order reaction, the time required for 99.9% of the reaction to complete is 10 times that required for half of the reaction to take place?

The integrated rate expression for first order reaction is
t= 2.303K1  log (aa-x)
where a= initial concentration of reactants
a-x = concentration of reactants left.

so if the 99.9% of the reaction is complete then 0.1 % of the reaction is left.
Let a= 100 , and if 0.1 % reaction is incomplete, then a-x would be 0.1
now, using formulae given above, we can calculate the time period of the reaction.
t99.9= 2.303K1 log(1000.1)

t99.9=2.303K1 log (1000)............................{log1000=3}


t99.9  = 2.303K1 ×3.................. (1)
now, calculating time period for 50% completion of reaction,
t502.303K1 log(10050)

t502.303K1 log(2)

t500.3010×2.303K1 ......................(2)
 Dividing equation 2 by 1
 t50t99.9 = 2.303×0.3010K1×K12.303×3 

 t50t99.9= 0.30103 

 t50t99.9= 0.1003 
therefore, t99.9 = 10 ×t50
 

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