what is the difference between electron affinity and electron gain enthalpy
The Electron affinity of a molecule or an atom is the energy change when an electron is added to the neutral atom to form a negative ion. This property can only be measured in an atom in gaseous state.
- X + e− → X−
The electron affinity, Eea, is defined as positive when the resulting ion has a lower energy, i.e. it is an exothermic process that releases energy:
- Eea = Einitial − Efinal
Also, electron affinity is often described as the amount of energy required to detach an electron from a single charged negative ion, i.e. the energy change for the process
A molecule or atom that has a positive electron affinity is often called an reactions.
but electron gain enthalpy refers to the tendency of an isolated gaseous atom to accept an additional electron to form a negative ion.
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