Mastering Organic Chemistry (Class XII)

Somak Chatterjee|Mar 9th, 2013 02:56pm

  • Focussing on NCERT questions: The NCERT Part – II comprises of organic chemistry and contributes to 28 marks in the examination.
  • An analysis of previous years’ question papers depicts that many questions are asked as it is from the NCERT textbooks.

The table given below shows the question numbers of the questions in the NCERT book which have been asked in the examination. Note that, many questions are being asked repeatedly.

Units

Marks

2012

2011

2010

2009

2008

2007

2006

Haloalkanes and Haloarenes

4

Example 10.2 (vi)

Table 10.1

Example 10.7

Example 10.6, 10.17

Ex 10.2 (i)10.9 (i), 10.14 (vii)

Alcohols, Phenols and Ethers

4

Exercise 11.5, 11.15

11.18 (ii), 11.31 (iv)

11.20 (ii, iv), 11.18 (i, iii)

11.3 (v)

11.3 (ii), 11.21 (ii, ii, vi)

11.22

Aldehydes, Ketones and Carboxylic Acids

6

Example 12.5 (i, iv),Exercise 12.10,Exercise 12.12, Exercise 12.13 (i, vi)

12.13 (i, iv), 12.16 (ii, iv), 12.17 (i, ii)

Fig 12.2, 12.11, 12.13 (iii, vii), 12.12 (i, ii)

12.16 (ii), 12.19, 12.17 (iv)

12.12 (ii), 12.17 (i, x, xi), 12.16 (ii, iii)

Table 12.1, 12.13 (i)

12.16 (ii), 12.13 (vii)

Amines

4

Exercise 13.7 (i and iii), Exercise 13.11 (ii, v)

13.4 (ii)

Table 13.1, 13.4 (i,ii, iii-a, iv)

Ex 13.4, 13.7 (iii, iv)

13.3 (I, iii, v)

13.12

13.2 (v)

Biomolecules

4

Exercise 14.12

14.12, 14.13

14.17, 14.22

14.12 (i), table 14.3

14.12 (i, iii), 14.10

14.12 (ii)

14.15, table14.3

Polymers

3

15.2

15.11

15.12

15.17

15.12, 15.16

15.12, 15.15

Chemistry in Everyday Life

3

Exercise 16.10

16.15

16.21 (i)

16.15, 16.17, 16.21 (i)

16.12, 16.22

16.15

So, mark these questions in the NCERT book and go through all the NCERT solutions thoroughly. For this you can also refer to the NCERT solutions section on meritnation.com

  • IUPAC Nomenclature questions: A conclusion from previous years’ papers is that, 90% of the questions related to nomenclature of organic compounds usually come from the tables of common and IUPAC names or in-text examples present in NCERT book. Below is a summarized chart of all the tables and in-text examples meant for nomenclature.

Haloalkanes and Haloarenes

Table 10.1, example 10.1 and example 10.2

Alcohols, Phenols and Ethers

Table 11.1, 11.2, example 11.1 and in-text question 11.3

Aldehydes, ketones and carboxylic acids

Table 12.1 and intext questions 12.1, Table 12.3 and in-text question 12.6

Amines

Table 13.1

Note: Do not leave even a single compound from the tables and in-text examples.

  • Name reactions: Important name reactions which have been asked previously are Sandmeyer reaction, Williamson synthesis, Riemer-Tiemann reaction, Kolbe’s reaction, Aldol Condensation, Cannizzaro Reaction, Clemmensen Reduction reaction, Hoffmann Bromamide reaction, Coupling reaction. So,we advise you to revise these reactions.
  • Distinction test: The distinction tests are usually asked between:
  • Aliphatic and aromatic compounds
  • Compounds having two different functional groups
  • Compounds having same functional group but different arrangement of atoms (e.g., 1°, 2°, 3°)

Steps for attempting these questions
Step – I: See how many marks are allotted to the question. Remember, 1 mark is for 1 test.
Step – II: Write the structural formulae of both the compounds.
Step – III: See where the two structures differ in.
Step – IV: Recall the reactions which you have studied.
Step – V: Apply those reactions in the compounds keeping in mind the skeletal structure they differ in.

  • Conversions: Conversion based questions are surely going to come in exams. Remember there can be multiple steps to reach the final product but the shortest and feasible steps have to be written in the answer-sheet.

Please note CBSE has yet not asked any conversion which consist of more than 3-steps.

Steps for attempting these questions
Step – I: Read the question very carefully.
Step – II: Write the starting compound on the left hand side and the final compound on the right hand side.
Step – III: See where do the two structure differ in.
(They mostly differ either in functional groups, number of carbon atoms or both)
Step – IV: Recall the reactions which you have studied.
Step – V: Apply those reactions in initial compound so as to reach to the final compound.

Expected areas from where questions can come in 2012

Unit

Expected areas from where questions can be asked in 2013 examination

Haloalkanes and Haloarenes

IUPAC Nomenclature, SN1 and SN2 reaction (Question: Which compound undergoes faster reaction?), DDT, Iodoform

Alcohols, Phenols and Ethers

IUPAC Nomenclature, Conversions, Alcohols – Boiling points and solubilities, Phenols-Acidic properties, Difference in the boiling points of ethers and alcohols, Williamson reaction, Reimer-Tiemann reaction

Aldehydes, Ketones and CarboxylicAcids

IUPAC Nomenclature, Nucleophilic addition on carbonyl carbon, Aldol Condensation, Cannizzaro reaction, Clemmensen reduction reaction, Acidity of carboxylic acids (Question: Arrange the following compounds in increasing/ decreasing order of their acidic trends.), Distinction tests, Conversions

Amines

IUPAC Nomenclature, Basicities of amines (Question: Arrange the following amines in increasing/ decreasing order of their basic strengths.), Hoffmann Bromamide reaction, Coupling reaction, Aniline -Insoluble in water and does not undergo Friedel Crafts reaction

Biomolecules

Glucose open chain and cyclic structure (Question: Why was the open chain structure of glucose unable to explain its properties?), Proteins-Primary, secondary, tertiary and quarternery structures, Vitamins – Sources and deficiency disease – table 4.3, nucleosides and nucleotides

Polymers

Elastomer, thermoplastic and thermosetting polymer, Rubber, Nylon 6, nylon 6,6, teflon, bakelite, Buna-N

Chemistry in Everyday Life

Detergents, Food preservatives, Enzymes, Antifertility drugs, Analgesics, Artificial sweetening agents, biodegradable and non-biodegradable detergents

To help all you students in this last stage of preparation, we are providing Conversion Schemes Distinction Tests, Name Reaction List and Name Reaction in Detail.

Follow these simple but smart ways and give your 100 % in the examination.

Best of Luck!
Team Meritnation

Add Comment Total Comments (14)

  • 1. purvesh  |  March 7th, 2014 at 10:01 pm

    Please Update The Expected Question Meritnation Team.

  • 2. Rahul Mishra  |  March 5th, 2014 at 9:19 pm

    please kindly update the above tables and things…………

  • 3. theressa  |  January 3rd, 2014 at 1:05 pm

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  • 4. arjun  |  August 1st, 2013 at 4:28 pm

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  • 5. Manish  |  March 12th, 2013 at 3:44 pm

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  • 6. VIVEK  |  March 11th, 2013 at 4:04 pm

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  • 7. Akanksha Payal  |  March 10th, 2013 at 7:57 pm

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  • 8. krishna  |  March 10th, 2013 at 7:18 pm

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  • 9. marwin  |  March 10th, 2013 at 6:34 pm

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  • 11. Vishnu  |  March 9th, 2013 at 10:27 pm

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  • 12. PRIYANKA PALIWAL  |  March 9th, 2013 at 9:28 pm

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  • 13. shyam  |  March 9th, 2013 at 7:31 pm

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  • 14. Mohit pareek  |  March 9th, 2013 at 5:52 pm

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