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Haloalkanes and Haloarenes

Classification: Mono, di and polyhalogen (tri, tetra, etc.)

 

(i) Alkyl halides or haloalkanes (R−X)  They form homologous series of general formula CnH2n+1X. They are further classified into primary, secondary, and tertiary.

 

(ii) Allylic halides  Compounds containing halogen atom bonded to an allylic carbon

 

(iii) Benzylic halides  Compounds containing halogen atom bonded to an sp3 hybridised carbon atom next to an aromatic ring

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