1.24g white phosphorous P4 was allowed to react with O2 to produce P4O6 an acidic oxide.The solution of P4O6 in water is acidic and is neutralized with NaOH.How many moles of NaOH are required to neutralize H3 PO3 generated in the above case?
The chemical reactions mentioned in above case are :
P4 + 3O2 → P4O6
P4O6 + 6H2O → 4H3PO3
2NaOH + H3PO3→ Na2HPO3 + 2H2O
Moles of NaOH (nNaOH) can be calculated as :
1 mol P4 ≡ 1 mol P4O6 ≡ 4 mol H3PO3
1 mol H3PO3 ≡ 2 mol Na OH
nNaOH =
= 1.24 g P4 * 1mol P4/124g P4 * 1mol of P4O6/1 mol P4
* 2 mol NaOH/1 mol of H3PO3
= 0.01 × 4 × 2
= 0.08 mol