1)The most volatile alkane is:

a) Neopentane b)isopentane

2) Methane cannot be formed by:

a) COCl2 b) CS2

3) Which of the following represents the most oxidised form of hydrocarbon R-CH3:

a) CO2 b)RCOOH

1) a) Neopentane is more volatile than isopentane since the boiling point of alkanes decreases on increased branching.

 

2) a) Methane cannot be formed by COCl2 since it can be formed from CS2. The reaction is as follows:

 

 

3) a) CO2 represents the most oxidized form of hydrocarbon.

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  1. A straight-chain alkane will have a boiling point higher than a branched-chain alkane due to the greater surface area in contact, thus the greater van der Waals forces, between adjacent molecules.

      since , in neopentane the branching is higher , its boiling point will be less than isopentane.

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