112 ml of a gas is produced at STP by the action of 412 mg of alcohol ROH with CH3Mgl. The molecular mass of alcohol is,
CH3Mgl + ROH -- > CH4(g) + R-OMg-l
A)32g
B)41.2g
C)82.4g
D)156g

ROH + CH3MgICH4 + RO-MgI+Volume of gas produced = 112 mLMass of alcohol used = 412 mg1 mole of alcohol produce 1 mole of CH4.So, 22.4 L CH4 will be produced by the molecular weight of alcohol.112 mL CH4 is produced from 412 mg of alcoholSo, 22400 mL of CH4 will be produced by = 412112×22400=82400 mg of alcohol = 82.4 g of ROHSo, molecular mass of alcohol will be = 82.4 g
Option C is correct.

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