20 ml mixture of CO and C2Hwas exploded with 50 ml of O2.The volume after explosion was 45 ml on shaking with NaOH solution only 15 ml O2 was left behind ,what were the volume of CO and C2H4 in mixture?

Dear Student,

Let the mixture contain y ml of C2H4 and x ml COC2H4 + 3O2  2CO2 + 2H2O    y                          2y   CO + 12O2  CO2     x                          x         NaOH absorbs the CO2 produced in the reactionTotal amount of CO2 produced = x+2y =(45-15) ml   and we know that, x+y=20 mlTherefore, (20-y)+2y=30or, 20+y=30or, y=10 mlTherefore, x=10 ml

Regards

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