4 mol of PCl5 is heated at constant temperature in a closed container . if degree of dissociation of pcl5 is 0.5 then calculate the total number of moles at equilibrium ?


Dear Student,


                    PCl5       PCl3  +   Cl2Initial            C                   0              0             At equil.   C(1-α)                      Total number of moles at equilibrium = C(1-α)++=C(1+α)Here, α= 0.5C=4Therefore, Total number of moles= 4(1+0.5)=4(1.5)=6 mol

Regards

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