69) How many electrons are present in 0.1 moles of P O 4 - 3 ions.
(A) 50   × 6 . 023   10 23
(B) 5 × 6 . 023   10 23
(C) 1 × 6 . 023   10 23
(D) 3 × 6 . 023   10 23

70) Esters are sweet smelling substances. These when treated with NaOH the
(i) Formation of alcohol and sodium salt
(ii) Formation of carboxylic and water
(iii) This reaction is known as sponification

(A) (i) and (ii) are wrong
(B) (ii)and (iii) are wrong
(C) Only (ii) is wrong
(D) Only (iii) is wrong

69. Number of moles = 0.1 Number of molecules = Mole × NA                      = 0.1 × 6.022 × 1023                            = 6.022 × 10221 molecule of PO43- has 15 + 4×8 + 3 = 50 electrons 6.022 × 1022 molecule of PO43- has = 50 × 6.022 × 1022                                                                   = 5 × 6.022 × 1023 Thus option B is correct.70) Esters on base hydrolysis produce sodium salt of the acid and alcoholThis reaction is called soaponification.RCOOR' +H2O NaOH RCOONa + R'OHSo the statement I and III are correct.Option C is correct

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