A hydrogen gas electrode is made by dipping platinum wire in a solution of HCl of pH = 10 and by passing hydrogen gas around the platinum wire at one atm pressure, The oxidation potential of electrode would be
1- 0.59V 2- 0.118V
3- 1.18V 4- 0.059V
Ans is - 0.59 V
As pH = 10
and pH = - log[H+]
10 = - log[H+]
[H+] =
Now according to Nernst equation,
Ecell = Eocell -
Half cell reaction is
H+(aq) + e- (g)
Thus n = 1 and
Now for this reaction E0cell = 0 V
So Ecell = 0 - 0.0591 log(1/10-10)
= - 0.0591 log 1010
= - 0.0591 x 10
Ecell = - 0.591 V
The correct option is (1).
As pH = 10
and pH = - log[H+]
10 = - log[H+]
[H+] =
Now according to Nernst equation,
Ecell = Eocell -
Half cell reaction is
H+(aq) + e- (g)
Thus n = 1 and
Now for this reaction E0cell = 0 V
So Ecell = 0 - 0.0591 log(1/10-10)
= - 0.0591 log 1010
= - 0.0591 x 10
Ecell = - 0.591 V
The correct option is (1).