Al is amphoteric. Why? Also show that it is amphoteric with suitable example reactions.

It reacts with acids to form Al3+ ions: 

Al2O3 + 6 H+ --> 2 Al3+ + 3 H2O 

It reacts with bases to form Al(OH)4- ion (that's 4 hydroxides and a 1- charge): 

Al2O3 + 2 OH- + 3 H2O --> 2 Al(OH)4- . 

Reaction with both acids and bases is what defines amphoteric.

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