Given, density of water = 1g/cm3
1 Litre = 1000 cm3
mass = density x volume = 1000 x1 = 1000g
also molar mass of water = 2*1 + 16 = 2+16 = 18g
no. of moles = given mass/molar mass = 1000/18 = 500/9 mol.
no of molecules in 1 mole= 6.022 * 1023
therefore, no. of molecules in 500/9 moles = 500/9 * 6.022 * 1023
=3.3456 * 1025