CH3CHO+2H^++2e^--->Ch3CH2OH
the half cell potential is -0.197V pH=7.calculate the half cell potential when pH is 6 and ethanol and acetaldehyde each has concentration 10^-5M

According to Nernst equationE= E0 - 0.0591n log [oxidised][reduced]-0.197  = E0 - 0.0591n log [oxidised][reduced]       = E0- 0.05912 log [1][H+]2 E0 =  -0.197 +   0.05912 log [1][H+]2     = -0.197 +   0.05912 log H+-2     = -0.197 -   0.05912 2 log H+      = -0.197 +0.0591 × pH      = -0.197 +0.0591 × 7        = 0.2167Using this value E= 0.2167 - 0.05912  log [1][H+]2    = 0.2167 -  0.05912  log H+-2     = 0.2167 +  0.05912  2 log H+     = 0.2167 -  0.05911   pH    = 0.2167 - 0.0591× 6   = -0.1379   

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