On chlorination of toulene the possible products are
1. one hydrogen replaced by Cl
2. two H replace by Cl
3. All H replaced by Cl
Note alkyl halide on treatment with Aq. NaOH gives alcohol (X replaced by OH) (nucliophillic substitution)
consider case 1 we get C6H5CH2Cl
consider case 2 we get 2 OH on same Carbon which is unstable so H20 gets eliminated which gives
Benzalhehyde
consider case 3 we get 3 OH on same C atom again H20 eliminated and we get Benzoic acid
check the options only only matching option is option d
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