CsCl crystallizes in a cubic cell that has a Cl- at each corner and Cs at the centre of the unit cell.if the radius of of Cs is 1.69Å and rcl - = 1.81Å, what is the edge length of unit cell?
For BCC ionic crystal (r+ + r-) = root 3 a /2 or a= 2(r+ + r-)/ root 3
=2(1.69+1.81)/root 3 = 4.04 Å
=2(1.69+1.81)/root 3 = 4.04 Å