Degree of dissociation of 0.1 M HCN solution is 0.01%. its ionisation constant would be
a)10-3                                b)10-5
c)10-7                                d)10-9

HCN is a weak acid, So, the equilibrium constant will be calculated by Ostwald dilution law.
Initial concentration = 0.1 MDegree of dissociation = 0.01% = 10-4                                                                HCN              H+           +      CN-Initial concentration at time, t=0      0.1M                     0                         0At time t=teq., concentration       0.1(1-10-4)          0.1×10-4     0.1× 10-4Keq=[H+][CN-][HCN] = 0.1×10-4×0.1×10-40.1×(1-10-4)=10-9
 

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