Derive the following:
1) Normality = (%age x density x 10) / Equivalent mass of solute
2) Relation between molarity and molality when density and molar mass of the solute is given.
1) We know,
2) Let w be the mass of solute dissolved in W grams of solvent so that the volume of solution is V.
Let M’ be the molar mass of the solute.
Therefore, Molarity
-------------(1)
And
Molality,
----------------(2)
Now, Density,
From equation (1),
------------------(3)
And from equation (2),
Therefore,
--------(4)
Dividing equation (4) by (3)
Or