Distinguish between n-type and p-type semi-conductors on the basis of energy band diagrams. Compare their conductivities at absolute zero temperature and at room temperature. 

Dear Student ,

N type : The impurity atoms added, provide extra electrons in the structure and are called donor atoms.The donor energy level is close to the conduction band and for away from the valence band. This small energy gap is only 0.045 eV and no of electron increases in conduction  band. As we can see in below diagram.





P type: ​The impurity atoms added, create vaccines of electrons (i.e. holes) in the structure and are called acceptor atoms.The holes are majority carriers and electrons are minority carriers.The acceptor energy level is close to the Valence band and for away from the Conduction band.The Fermi-energy level lies in between the acceptor energy level and valence band. we can see the energy level from below diagram.

The electrical conductivity of a semiconductor at absolute zero of temperature is zero.

For equal doping, an n-type semi conductor will have more conductivity than a p-type semiconductor, at room temperature.

 

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N-type band;​The addition of donor impurities contributes electron energy levels high in the semiconductor band gap so that electrons can be easily excited into the conduction band. This shifts the effective Fermi Level to a point about halfway between the donor levels and the conduction band. 

P-type band-​The addition of acceptor impurities contributes hole levels low in the semiconductor band gap so that electrons can be easily excited from the valence band into these levels, leaving mobile holes in the valence band. This shifts the effective Fermi Level to a point about halfway between the acceptor levels and the valence band
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