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Dear student

Given that Conc. HNO3 = 63%
& density of HNO3 = 1.4 g/ml

Now, Take 1.0 L of this solution having mass = 1,400 g

Mass of HNO3 in 1.0 L = 63100 x 1400 = 882 g

Molar mass HNO3 = 1 + 14 + 3 x 16 = 63 g/mol

moles of  HNO3 in 882g = 882 g63 g mol-1 = 14.0 mol

Molarity of solution = 14.0 M

Calculate volume required to produce 250mL of 1.20M solution by using molarity equation

M1V1 = M2V2

14.0 M x V1 = 1.20 M x 250 mL

V1 = 1.20 M x 250 mL14.0 M

V1 = 21.4 mL

Volume required = 21.4 mL
Hence option (B) is correct

Regards

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