First electron affinity for oxygen is exothermic but second electron affinity for oxygen is endothermic.explain Share with your friends Share 4 Geetha answered this Electron affinity is the energy change in an atom when an electron is added to a neutral gaseous atom.In oxygen O + e- → O-First EA = -142 kJ/molThe first electron affinity is negative showing its exothermic, energy is released during the addition of electron to the neutral atom. O- + e- → O2-Second EA = + 844 kJ/molThe second reaction is endothermic showing that energy is absorbed to perform this change.The second electron affinity of oxygen is high because the electron is added forcefully to a small, very dense space. As well as its added to an already negative ion. -5 View Full Answer