• From the following molar conductivities at infinite dilution calculate limiting molar conductivity for NH4OH....
  • Limiting molar conductivity for Ba(OH)2=457.6 ohm-1 cm2 mol-1
  • ​​​Limiting molar conductivity for Bacl2=240.6 ohm-1cm-1
  • Limiting molar conductivity for NH4Cl=129.8 ohm-1cm2 mol-1

The formation of BaCl2 is represented asBa(OH)2 +2NH4Cl 2NH4OH + BaCl2λMBa(OH)2  +2 λMNH4Cl  = 2 λMNH4OH  + λMBaCl2  457.6 + 2 × 129.8 = 2 × λMNH4OH  + 240.62 λMNH4OH  =476.6λMNH4OH  =476.62 =238.3 ohm-1cm2mol-1

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limiting molar conductivity for NH4OH =LMC for (NH4^+) +(OH^-)
ADDING bacl2 in the solution
now limiting molar conductivity [ NH4CL+1/2 Ba(OH)2  -Bacl2]
substitute the values u will get ans as 118 ohm-1 cm2 mol-1
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