- give reasons:
- HF is stored in a WAX coated glass bottles.
- When NaBr is heated with conc.H2SO4, Br2 is produced but when NaCl is heated HCl is produced.
2. How is XeO3 prepared? Reprsent with the chemical equations.
Hi,
Hydrofluoric acid attacks glass with the formation of fluorosilicate ions [SiF6]2-.Thus it is stored in wax coated glass bottles to prevent the reaction.
SiO2 + 6HF → [SiF6]2- + 2H+ + 2H2O
The reduction potential of Br2/Br- is less as compared to Cl2/Cl-. Thus the tendency of Br- to oxidise is more as compared to Cl-.
Here's the reaction.
3XeF4 + 6H2O → 2Xe + XeO3 + 12HF + 3/2 O2
XeF4 reacts violently with water to form XeO3.