how would justify rusting as a chemical change?

Rusting of Iron is a chemical change as..

  • It involves a chemical reaction

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  • During rusting a new compound  called rust is formed with molecular formula... .
  • Rusting of iron is irreversible change  i.e. Rust once formed can not be converted back into iron.

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Rust is another name for iron oxide which occurs when iron or an alloy that contains iron, like steel is exposed to oxygen and moisture for a long period of time.  Over time the oxygen combines with the metal at an atomic level, forming a new compound called an oxide and weakening the bonds of the metal itself.  Although some people refer to rust generally as oxidation that term is much more general: although rust forms when iron undergoes oxidation, not all oxidation forms rust.  Only iron or alloys that contain iron can rust, but other metals can corrode in similar ways. The main catalyst for the rusting process is water.  Iron or steel structures might appear to be solid, but water molecules can penetrate the microscopic pits and cracks in any exposed metal.  The hydrogen atoms present in water molecules can combine with other elements to form acids, which will eventually cause more metal to be exposed.

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Iron reacts with oxygen in presence of moisture and a totally new substance that is rust or iron oxide is formed. Also this process is irriversible. That's why formation of  rust is called a chemical change.

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 rusted iron cannot be reversed back into new iron. so it is a chemical change

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