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Solution:

The correct option is (A).
The complex formed by the nitrogenase enzyme (nitrogen-fixing enzyme) is sensitive to oxygen. It gets irreversibly inactivated when exposed to even low concentrations of O2. 
Enzyme nitrogenase evolved during the pre-oxygenated state of the atmosphere on earth. Diazotrophic organisms like Rhizobium had to evolve mechanisms to protect nitrogenase from inactivation after the appearance of oxygen on earth.
 

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