Name the physical quantity whose S.I unit is VM.is or scalar or vector

No important physical quantity is measured in volt meter (VmVm).

If you are looking for volt/meter (Vm−1Vm−1), then that is the unit of electric field. Electric field is the gradient of electric potential. 
E⃗ =−∇ϕE→=−∇ϕ
The gradient operator has units of m−1m−1 and electric potential is measured in volt (V). Hence Vm−1Vm−1.
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 physical quantity is measured in volt meter (VmVm). If you are looking for volt/meter (Vm−1Vm−1), then that is the unit of electric field. Electric field is the gradient of electric potential
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No important physical quantity is measured in volt meter (VmVm). If you are looking for volt/meter (Vm−1Vm−1), then that is the unit of electric fieldElectric field is the gradient of electric potential. E⃗ =−∇ϕE→=−∇ϕ. 
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electric flux=E.S=(V/L).S 
                          =(V/m).mm =Vm
electric flux is the quantity mesured in Vm. it is scalar
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Vm is the SI unit of Electric Flux
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