P + O3-------) P2O5 + O2
balancee yheequation by oxidation number method

Dear Student,

Please find below the solution to the asked query:

Skeletal reaction: P + O3 ----> P2O5 + O2
Oxidation No.      0     0          +5  -2    0

Here, P oxidises from 0 to +5 and O reduces from 0 to -2.

So, the increase in oxidation number of +5 per atom can be balanced with decrease in oxidation number of -2 per atom if P atoms are multiplied by 2 and O3 by 5.

The equation then will be:  2P + 5O​3 ---> P2O5 + 5O2

Hope this information will clear your doubts about Redox Reactions.
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