please answer my question as soon as possible. i have my exams tomorrow

a)Combustion of 0.2000g of vitamin C gives 0.2998g of CO2

and 0.819g of H2O. What is the empirical formula of vitamin C?

b)4 litres of water are added to 2L of 6 molar HCl solutions.

What is the molarity of resulting solution?

a)
Mass of water produced in this reaction must be 0.0819g and not 0.819g.
Given that vitamin C on combustion gives carbon dioxide and water.Let vitamin C is X.
X (s) + O2(g) CO2​ (g) + H2O (l)
0.2000 g           0.2998g     0.0819g



Molar mass of CO2 = 12 + 2×16= 44 g
Amount of carbon in 44 g CO2 = 12 g
Amount of carbon in 0.2998g  CO2 = 1244×0.2998 g​ =0.0818 g

Molar mass of H2O = 1×2 + 16= 18 g
Amount of hydrogen in 18 g 
H2O = 2 g
Amount of hydrogen  in 0.0819 g H2O​ = 218×0.0819 g​ =0.0091 g

Percentage of carbon in fuel gas = 0.08180.2000×100 = 40.9 %

Percentage of hydrogen in compound = 0.00910.2000×100 = 4.55 %​

Thus Percentage of oxygen in the compound= 100 - (40.9 + 4.55) = 54.55 %

 
 
Element Atomic mass of element Percentage  Moles of the constituents  Molar ratio Simple whole number ratio
C 12 40.9 40.912=3.408
3.4083.408=1
1×3=3
H 1 4.55 4.551=4.55 4.553.408=1.33
1.33×3=4
O 16 54.55
54.5516=3.41
3.413.408=1.00 1×3=3

Thus the simple ratio of C:H:O is 3:4:3

Thus empirical formula of the compound = C3H4O3
 


b)
First we find that how many moles of HCl are there,We know, Molarity=  Moles of soluteVolume of solution in LitreNow it is given that Molarity = 6MVolume= 2 LThus 6=Moles of HCl2Moles of HCl = 6×2 = 12 molesNow 4 L of water is added to the solution therefore now the total volume of solution becomes 2+4 =6LBut Number of moles of HCl remain same Thus, now 12 moles of HCl are present in 6 L solution.Therefore molarity becomes:Molarity=  Moles of HClVolume of solution in LitreMolarity=  12 moles6 L             =2 M
Thus now the molarity of the solution is 2 M

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