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Dear student 
Please find your answer below to the asked query 

100 gm of solid phosphorus = 100/31 = 3 moles
 
  1 mole of phosphorus = 6.022x1023 molecules
 
  3 mole of phosphorus = 3 x 6.022x1023
 
  = 18.066 x 1023 molecules

 

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