Please explain with proper solution     

57. For preparing a buffer solution of pH = 7.0, which buffer system you will choose?

( 1 )   H 3 PO 4 ,   H 2 PO 4            

( 2 )   H 2 PO 4 ,   HPO 4 2        

( 3 )   HPO 4 2 ,   PO 4 3      
        
( 4 )   H 3 PO 4 ,   PO 4 3      

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