Pls tell how to do Qn 1

Dear Student,
1 mole of PbS = 207 + 32 = 239 g
1 mole of PbO = 207 + 16 = 223 g

(i) 239 g of PbS is equivalent to 1 mole of PbS. So, 478 g of PbS is equivalent to 2 moles of PbS. 
2 moles of PbS produces 2 moles of PbO. Thus,
478 g of PbS produces 2×223g=446g of PbO.
(ii) 1 mole of any gas at S.T.P. occupies 22.4 litres.
2 moles of PbS produces 2 moles of SO2.
Thus, 2×22.4 litres of SO2 is produced by 478 g of PbS at STP.
5.6 litres 
of SO2 is produced by 4782×22.4×5.6=59.75 g of of PbS at STP.
(iii) 2 moles of
SO2 requires 3 moles of O2.
22.4 litres of SO2 = 1 mole of  SO2 
5.6 litres of SO25.622.4=14moles
So, 14 moles of SO2=32×14=38moles of O2.
Regards

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