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Dear student
  • Since the SN2 proceeds through a backside attack, if a stereocenter is present the SN2 reaction will give inversion of stereochemistry.
  • By contrast, if the SN1 leads to the formation of a stereocenter, there will be a mixture of retention and inversion since the nucleophile can attack from either face of the flat carbocation
So we will find from the above options which is most favorable for SN
 SN1 formation takes when the carbocation formed is very stable so in option (3) there is formation of benzylic carbocation which is very stable hence that will be the correct option.

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