Predict the feasibility of a reaction when
(i) both delta H and delta S increases.
(ii)both delta H and delta S decreases.
(iii)delta H increases but delta S decreases.
(iv)delta H decreases but delta S increases.
We know,
Where,
A reaction is feasible if is negative.
(i) When both delta H and delta S increases, is positive and is also positive. In this case, for to be negative; T should be more than . This is possible when temperature is high. So, the reaction will be feasible at high temperature.
(ii)When both delta H and delta S decreases, is negative and is also negative. In this case, for to be negative; T should be less than . This is possible when temperature is low. So, the reaction will be feasible at low temperature.
(iii) When delta H increases but delta S decreases, is positive and is also negative. In this case, cannot be negative any temperature. So, the reaction will not be feasible at any temperature.
(iv) When delta H decreases but delta S increases, is negative and is positive. In this case, will be negative at all temperatures. So, the reaction will be feasible at all temperatures.
Where,
A reaction is feasible if is negative.
(i) When both delta H and delta S increases, is positive and is also positive. In this case, for to be negative; T should be more than . This is possible when temperature is high. So, the reaction will be feasible at high temperature.
(ii)When both delta H and delta S decreases, is negative and is also negative. In this case, for to be negative; T should be less than . This is possible when temperature is low. So, the reaction will be feasible at low temperature.
(iii) When delta H increases but delta S decreases, is positive and is also negative. In this case, cannot be negative any temperature. So, the reaction will not be feasible at any temperature.
(iv) When delta H decreases but delta S increases, is negative and is positive. In this case, will be negative at all temperatures. So, the reaction will be feasible at all temperatures.