Q.27. An organic liquid, A in immiscible with water. When boiled together with water, the boiling point is 90 ° C at which the partial vapour pressure of water is 526 mm Hg. The superincumbent (atmospheric) pressure is 736 mm Hg. The weight ratio of the liquid and water collected is 2.5 : 1. Wha is the molecular weight of liquid.

The solution is as follows:

1. The relation is :

     W1W2=M1×P01M2×P02  M1 = 2.5×18×5261×(736-526)=112.7 g/mol
 

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