Q. In which of the following compounds iron has lowest oxidation state ? 


1 .   F E S O 4 ( N H 4 ) 2 S O 4 . 6 H 2 O 2 .   K 4 F e ( C N ) 6 3 .   F e C O 5 4 .   F e 0 . 94 O

The solution is as follows:

1. The correct option is (c) Fe(CO)5.

2. This is because, the carbonyl compounds of transition metals are formed in 0 or lowest oxidation state of the metal atom.
         As we know, charge on CO is 0, and molecule is neutral, so Fe will also have neutral or 0 oxidation state.

3. In other molecules, Fe is involved in ionic bonding and thus, posses +2 or +3 oxidation state.

  • -1
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