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A-8.      A sample of  O 2  gas is collected over water at  23 ° C  at a barometric pressure of 751 mm Hg (vapour pressure of water at  23 ° C  is 21 mm Hg). The partial pressure of   O 2  gas in the sample collected is 

(1)      21 mm Hg              (2)    751 mm Hg            (3)    0.96 atm          (4)    1.02 atm

Dear Student
Using the Dalton's law 
PT = Poxygen +Pwater 
At 23.0 o C the vapor pressure of water is 21mmHg
751mmHg = Poxygen + 21 mmHg
Poxygen = 751 mmHg - 21 mmHg
Poxygen =730 mmHg

Convert the partial pressur of oxygen in to atmosphere
(730 mmHg) (1 atm / 760 mmHg) = 0.96 atm
​therefore,option 3 is correct
Regards

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