Solve this:
Q. In a vessel containing S O 3 ,   S O 2   a n d   O 2 at equilibrium, some helium gas is introduced so that the total pressure increases while temperature and volume remain constant. According to Le-Chatelier principle, the dissociation of S O 3
(1) Increases
(2) Decreases
(3) Remains unaltered
(4) None of these

Dear Student,

SO2 + 12O2   SO3The increase in pressure favours the side where less number of moles of gas are present. Here, lesser moles are presen tin the forward reaction. Therefore, by increasing pressure reaction will move forward. Hence, dissociation of SO3 will decrease and formation of SO3 will increase. So, correct answer is (2)

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