The enthalpy of solution of BaCl2 (s) and BaCl2.2H2O(s) is –x kJ mol–1 and y kJ mol–1 respectively then enthalpy of hydration of BaCl2(s) to BaCl2.2H2O(s) is given by
(1) (x – y) kJ             (2) (y – x) kJ               (3) (x + y) kJ                (4) –(x + y) kJ

Dear Student,

Enthalpy of hydration= Enthalpy of solution of BaCl2-enthalpy of solution of BaCl2.2H2O                                     =-x-y                                     =-(x+y) kJ/molHence, correct ansnwer is (4)

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