To identify the contents of an unlabelled cylinder of gas,a sample was collected and found to have a density of 5.380g/L at 15 degreesC and 736mm Hg pressure.what is the molar mass of the gas?

Use the ideal gas equation : PV = nRT 
n (number of moles) = m (given mass)/ Molar mass (M)
PV = (m/M)RT 
Or,
M= mRT/PV........(1)
​m/V = Density D , so eq (1) can be written as :
M = DRT/P ......(2)
Now we have to calculate the gas constant R in term of mm Hg pressure using the formula given below
R= PV/nT
R = 760 mmHg x 22.4L / 1 mole x 273 K = 62.4 mm Hg L/ mole K 
T = 15 º C = (15+273) K = 288 K 
D = 5.38 g/L

Putting the values in eq(2) we get :
M = 5.380 g / L x 62.4 mm Hg L/mole K x 288 K / 736 mm Hg = 131.4 g / mole

The Molar mass of unknown gas is 131.4 g/mole

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