what is half.cell reaction ?

Half cell reactions: A half reaction is either the oxidation or reduction reaction component of a redox reaction. A half reaction is obtained by considering the change in oxidation states of individual substances involved in the redox reaction.

Placing a piece of reactant in an electrolyte solution makes a half cell. Unless it is connected to another half cell via an electric conductor and salt bridge, no reaction will take place in a half cell.

  • On the cathode, reduction takes place.

Oxidant + n e- → Reductant
Example: Cu2+ + 2 e  Cu
Cu2+ is the oxidizing agent and Cu the reducing agent.

  • On the anode, oxidation takes place.

Reductant n e- + Oxidant
Example: Zn  Zn2+ + 2 e-.
Zn is the reducing agent, and Zn2+ the oxidizing agent.

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