What is the difference between peroxide ion and super oxide ion??

Dear Student,

Superoxides: These are compounds that possess the superoxide anion with the chemical formula O2 -.With one unpaired e-, the superoxide ion is a free radical and is paramagnetic in nature. In the case of superoxides like CsO2,NaO2, KO2, RbO2 each oxygen atom is assigned an oxidation state of -1/2.

Peroxides: These are compounds containing an oxygen-oxygen single bond or the peroxide anion [O-O]2-.The O-O group is called the peroxide group. In case of peroxides H2O2, Na2O2 each oxygen atom is assigned an oxidation state of -1.

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Peroxide and superoxide are oxides containing oxygen atoms. The main difference between peroxide and superoxide is that the oxidation state of oxygen in peroxide is -1 whereas the oxidation state of oxygen in superoxide is -1/2.
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