which is correct???

Solution:

Electron transport chain can be described as the series of reactions in which electrons are passed from one carrier to another, and finally to oxygen, resulting in the formation of water as well as NADH and FADH2 are oxidized to release the energy stored in them. Complex V of ETS  is called ATP Synthase which is responsible for synthesis of ATP from ADP and inorganic phosphate with the help of oxidative phosphorylation. Complex III is responsible for pumping protons through the membrane and transfers electrons to cytochrome c to the IV complex.
Hence, the wrong match is (4)  and the correct option.

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