Why CO is more stronger ligand than NH3?

The field created by the Ligand CO is stronger than the ligand NH3. Consequently the splitting of d-orbital created by CO is larger than the NH3. Hence CO is more stronger ligand than the NH3.

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Quite appreciable answer.

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In formation of a coordination compound ligand CO acts simultaneously as a sigma base as well as pi acids as it accepts a pair of electrons into its vacant anti bonding orbital from a filled d-orbital of metal to form a pi bond.
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Page 255 1st paragraph :P 
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CO has empty π-orbitals which overlap with filled d-orbitals of transition metals and form π-bonds by back bonding. These π-interactions increase the value of crystal field stabilization energy. As NH3 can't form π bonds by back bonding, therefore CO is stronger ligand than NH3.
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pulsar ans is more appreciable
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The metal carbon 'pi' bond is formed by the donation of a pair of electron from field d-orbital of carbon monoxide (co). the metal to legand bonding creates a synergic effect which makes metal carbonyl bond strong than NH3
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In CO lone pair of electron to be used for coordination terms from sigma antibonding 2S, whereas in NH3 lone pair is forn Sp3 orbital and is less easily available for coordination , therefore CO is stronger legand than NH3.
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